ASTM D6729 Method for Individual Components in Spark Ignition Engine Fuels
ASTM D6729 Standard Test Method for Determination of Individual Components in Spark Ignition Engine Fuels by 100 Metre Capillary High Resolution Gas Chromatography
4. Summary of Test Method
4.1 Representative samples of the petroleum liquid are introduced into a gas chromatograph equipped with an open tubular (capillary) column coated with the specified stationary phase. Helium carrier gas transports the vaporized sample through the column, in which it is partitioned into individual components which are sensed with a flame ionization detector as they elute from the end of the column. The detector signal is recorded digitally by way of an integrator or integrating computer. Each eluting component is identified by comparing its retention time to that established by analyzing reference standards or samples under identical conditions. The concentration of each component in mass % is determined by normalization of the peak areas after correction of selected components with detector response factors. The unknown components are reported individually and as a summary total.
5. Significance and Use
5.1 Knowledge of the specified individual component composition (speciation) of gasoline fuels and blending stocks is useful for refinery quality control and product specification. Process control and product specification compliance for many individual hydrocarbons may be determined through the use of this test method.
