ASTM D5186 Determination of Aromatic Content and Polynuclear Aromatic Content
ASTM D5186 Standard Test Method for Determination of the Aromatic Content and Polynuclear Aromatic Content of Diesel Fuels and Aviation Turbine Fuels By Supercritical Fluid Chromatography
4. Summary of Test Method
4.1 A small aliquot of the fuel sample is injected onto a packed silica adsorption column and eluted using supercritical carbon dioxide mobile phase. Monoaromatics and polynuclear aromatics in the sample are separated from nonaromatics and detected using a flame ionization detector.
4.2 The detector response to hydrocarbons is recorded throughout the analysis time. The chromatographic areas corresponding to the monoaromatic, polynuclear aromatic, and nonaromatic components are determined and the mass % content of each of these groups in the fuel is calculated by area normalization.
5. Significance and Use
5.1 The aromatic hydrocarbon content of motor diesel fuels is a factor that can affect their cetane number and exhaust emissions. The aromatic hydrocarbon content and the naphthalenes content of aviation turbine fuels affect their combustion characteristics and smoke-forming tendencies. These properties represent specifications for aviation turbine fuels (see Specification D1655).
5.2 The United States Environmental Protection Agency (USEPA) regulates the aromatic content of diesel fuels. California Air Resources Board (CARB) regulations place limits on the total aromatics content and polynuclear aromatic hydrocarbon content of motor diesel fuel, thus requiring an appropriate analytical determination to ensure compliance with the regulations. Producers of diesel fuels will require similar determinations for process and quality control. This test method can be used to make such determinations.
5.3 This test method is applicable to materials in the boiling range of motor diesel fuels and is unaffected by fuel coloration. Test Method D1319, which has been mandated by the USEPA for the determination of aromatics in motor diesel fuel, excludes materials with final boiling points greater than 315°C (600°F) from its scope. Test Method D2425 is applicable to the determination of both total aromatics and polynuclear aromatic hydrocarbons in diesel fuel, but is much more costly and time-consuming to perform.
5.4 Results obtained by this test method have been shown to be statistically more precise than those obtained from Test Method D1319 for typical diesel fuels, and this test method has a shorter analysis time. Cooperative study data have found this test method to be more precise than the published precision of Test Method D1319 when applied to aviation turbine fuels and diesel fuels. Results from this test method for total polynuclear aromatic hydrocarbons are also expected to be at least as precise as those of Test Method D2425.